SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.053M) Tue Feb 23 08:56:23 2021 No. of days remaining = 364 Empirical Formula: Os6 Cl24 = 30 atoms MERS=(3,1,1) UHF MS=12 OPEN(6,12) PDBOUT CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Catena-di-mu-chloro-dichloroosmium(IV) (OsCl4) GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = 20733.02193 KCAL/MOL = 86746.96375 KJ/MOL Calculated Heat of Formation is very large, re-run using keyword 'CHECK' H.o.F. per unit cell = 3455.50365 KCAL, for 6 unit cells, unit cell = Os1 Cl4 TOTAL ENERGY = -7778.01276 EV ELECTRONIC ENERGY = -1107738.79200 EV CORE-CORE REPULSION = 1099960.77925 EV VOLUME OF UNIT CELL = 14489.923 CUBIC ANGSTROMS DENSITY = 0.076 GRAMS/CC A = 14.536 ANGSTROMS B = 37.597 ANGSTROMS C = 30.651 ANGSTROMS ALPHA = 113.272 DEGREES BETA = 74.460 DEGREES GAMMA = 85.334 DEGREES VOLUME OF CLUSTER = 43469.76947 ANGSTROMS**3 =26178.089 CM**3/MOLE GRADIENT NORM = 4.98066 = 0.90934 PER ATOM (SZ) = 12.000000 Average over configurations used, so (S**2) is not meaningful NO. OF ALPHA ELECTRONS = 120 NO. OF BETA ELECTRONS = 96 CHARGE ON SYSTEM = 6 IONIZATION POTENTIAL = 292.500874 EV ALPHA SOMO LUMO (EV) = -292.907******* BETA SOMO LUMO (EV) = -292.501******* MOLECULAR WEIGHT = 1992.0720 Pressure required to constrain translation vectors Tv( 31) Pressure: 0.00 GPa Tv( 32) Pressure: 0.01 GPa Tv( 33) Pressure: 0.00 GPa SCF CALCULATIONS = 89 WALL-CLOCK TIME = 5 MINUTES AND 25.014 SECONDS COMPUTATION TIME = 5 MINUTES AND 22.542 SECONDS FINAL GEOMETRY OBTAINED MERS=(3,1,1) UHF MS=12 OPEN(6,12) PDBOUT CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Catena-di-mu-chloro-dichloroosmium(IV) (OsCl4) Os -5.54795539 +1 -0.47671376 +1 -2.84814628 +1 Cl -7.48295242 +1 3.30120389 +1 0.83870192 +1 Cl -3.97075514 +1 5.94935739 +1 2.34944359 +1 Cl -4.58999591 +1 -1.77762194 +1 -4.54635037 +1 Cl -5.14553726 +1 0.99941670 +1 -0.00831348 +1 Cl -6.92023007 +1 4.55036391 +1 4.05319111 +1 Cl -7.31931550 +1 6.71903254 +1 1.41381801 +1 Cl -6.48861296 +1 -2.29522014 +1 -1.69792878 +1 Cl -7.49251753 +1 0.01615198 +1 -4.05473645 +1 Os -6.03472798 +1 4.79114347 +1 1.87648547 +1 Os -1.70893616 +1 1.43238039 +1 -0.18095113 +1 Cl -1.22150370 +1 5.03543783 +1 0.83206347 +1 Cl 1.27434981 +1 7.29793922 +1 2.68393598 +1 Cl 0.21132454 +1 0.60946936 +1 -1.23990952 +1 Cl -0.50588623 +1 2.11050257 +1 1.69686383 +1 Cl -3.90878033 +1 2.83750926 +1 0.44834275 +1 Cl -0.78592290 +1 8.93159347 +1 0.68944779 +1 Cl -2.22848476 +1 -0.61623327 +1 0.89257694 +1 Cl -3.06930891 +1 0.35140264 +1 -2.16234161 +1 Os -0.91798489 +1 7.07510192 +1 2.02886912 +1 Os 13.91283970 +1 0.60529300 +1 1.77952849 +1 Cl 14.78836870 +1 3.76353767 +1 3.11304440 +1 Cl 17.61215580 +1 7.00112197 +1 4.77161470 +1 Cl 14.50315185 +1 0.69094589 +1 -0.49058692 +1 Cl 15.92304446 +1 0.66602682 +1 2.98187397 +1 Cl 14.71499319 +1 5.77521209 +1 6.21621032 +1 Cl 14.57675964 +1 7.46961904 +1 3.18666982 +1 Cl 13.01804399 +1 -1.55767684 +1 1.91231754 +1 Cl 12.04910560 +1 2.03094801 +1 1.93402134 +1 Os 15.81830098 +1 5.68667265 +1 4.12520669 +1 Tv 42.91996046 +1 1.85768803 +1 -7.48514894 +1 Tv 5.37621208 +1 -37.01349940 +1 3.82485286 +1 Tv 2.87822862 +1 9.73042367 +1 -28.92251002 +1